# Model In pump-probe time resolved spectroscopy, we usually model the dynamics as sum of the exponential decay. For simplicity, I will consider one exponential decay model. \begin{equation*} {Model}(t) = \begin{cases} 0& \text{if $t<0$}, \\ \exp(-kt)& \text{if $t \geq 0$}. \end{cases} \end{equation*} where $k$ is rate constant, inverse of the life time.